118. Zexian Li and Zhuangzhi Shi,* Late-Stage Diversification of Phosphines by CH Activation: A Robust Strategy for Ligand Design and Preparation, Acc. Chem. Res. DOI:10.1021/acs.accounts.4c00020.


117. Xueli Lv, Minyan Wang, Yue Zhao and Zhuangzhi Shi,* P(III)-Directed Asymmetric C–H Arylation toward Planar Chiral Ferrocenes by Palladium Catalysis, J. Am. Chem. Soc. 2024, 146, 3483.


116. Zexian Li, Weipeng Xu, Shuaishuai Song, Minyan Wang,* Yue Zhao and Zhuangzhi Shi,* Enantioselective Rhodium-Catalyzed CH Arylation Enables Direct Synthesis of Atropisomeric Phosphines, Angew. Chem. Int. Ed. 2024, 63, e202316035.


115. Linlin Ding, Yue Zhao, Hongjian Lu, Zhuangzhi Shi and Minyan Wang,* Nickel-Catalyzed Asymmetric Propargyl-Aryl Cross-Electrophile Coupling, Angew. Chem. Int. Ed. 2024, 63, e202313655.



114. Zexian Li, Minyan Wang, Youqing Yang, Yong Liang, Xiangyang Chen, Yue Zhao, K. N. Houk and Zhuangzhi Shi,* Atroposelective Hydroarylation of Biaryl Phosphines Directed by Phosphorus Centres, Nat. Commun. 2023, 14, 8509.


113. Wang Jiang,§ Xiuxiu Yang,§ Lin Lin, Chaoguo Yan,* Yue Zhao, Minyan Wang and Zhuangzhi Shi,* Merging Visible Light Photocatalysis and P(III)-Directed C–H Activation by a Single Catalyst: Modular Assembly of P-Alkyne Hybrid Ligands, Angew. Chem. Int. Ed. 2023, 62, e202309709.


112. Tianhang Wang,§ Zheng-Jun Wang,§ Minyan Wang,* Lei Wu, Xiaowu Fang, Yong Liang, Jiahang Lv and Zhuangzhi Shi,* Metal-Free Stereoconvergent C–H Borylation of Enamides, Angew. Chem. Int. Ed. 2023, 62, e202313205.


111. Wang Jiang, Jingyi Bai, Jiahang Lv, Yue Zhao, Chaoguo Yan* and Zhuangzhi Shi,* Metal-Free Directed C–H Borylation of Indoles at the Sterically Congested C2 Position, Synlett 2023, 34, 2220.


110. Longlong Xi, Minyan Wang, Yong Liang, Yue Zhao and Zhuangzhi Shi,* Tunably Strained Metallacycles Enable Modular Differentiation of Aza-Arene C–H Bonds, Nat. Commun. 2023, 14, 3986.


109. Chong Lian,§ Longlong Xi,§ Yu Yuan,* Zhuangzhi Shi* and Minyan Wang,* Copper-Catalysed Controllable Hydrodefluorination of Trifluoromethylated Alkenes, Org. Chem. Front. 2023, 10, 3811.


108. Wang Jiang and Zhuangzhi Shi,* Recent Progress in meta-/para-Selective Aromatic C–H Borylation, Chin. J. Org. Chem. 2023, 43, 1691.

107. Jieshuai Xiao,§ Minyan Wang,§ Xuwen Yin, Shuo Yang, Pei Gu, Xueli Lv, Yue Zhao and Zhuangzhi Shi,* Enantioselective Reductive (Hetero)Arylation of Cyclic N-Sulfonyl Imines by Cobalt Catalysis, Angew. Chem. Int. Ed. 2023, 62, e202300743.


106. Ronghui Huang,§ Minyan Wang,§ Hong Deng, Jingkai Xu, Hong Yan,* Yue Zhao and Zhuangzhi Shi,* Stereospecific Nickel-Catalyzed [4+2] Heteroannulation of Alkynes with Aminophosphanes, Sci. Adv. 2023, 9, eade8638.


105. Tianhang Wang,§ Minyan Wang,§ Yandong Wang, Mingjie Li, Yuan Zheng, Qianwei Chen, Yue Zhao and Zhuangzhi Shi,* Ligand Cooperativity Enables Highly Enantioselective C-C σ-Bond Hydroboration of Cyclopropanes, Chem 2023, 9, 130.


104. Lin Lin,§ Xue-jun Zhang,§ Xinyu Xu, Yue Zhao and Zhuangzhi Shi,* Ru3(CO)12-Catalyzed Modular Assembly of Hemilabile Ligands by C–H Activation of Phosphines with Isocyanates, Angew. Chem. Int. Ed. 2023, 62, e202214584.



103. Longlong Xi, Liting Du and Zhuangzhi Shi,* Nickel-Catalyzed Reductive Cross-Coupling of Polyfluoroarenes with Alkyl Electrophiles by Site-Selective C–F Bond Activation,Chin. Chem. Lett. 2022, 33, 4287.


102. Lei Wu, Minyan Wang,* Yong Liang and Zhuangzhi Shi,* Ligand-Controlled Palladium-Catalyzed Regiodivergent Defluorinative Allylation of gem-Difluorocyclopropanes via σ-Bond Activation, Chin. J. Chem. 2022, 40, 2345.


101. Jiefeng Hu, Jiahang Lv and Zhuangzhi Shi,* Emerging Trends in C(sp3)–H Borylation, Trends Chem. 2022, 4, 685.


100. Ziqi Zhu and Zhuangzhi Shi,* Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides, Chin. J. Org. Chem. 2022, 42, 1872 (Highlight).

99. Dingyi Wang,§ Mingjie Li,§ Chengdong Shuang, Yong Liang, Yue Zhao, Minyan Wang and Zhuangzhi Shi,* Rhodium-Catalyzed Selective Direct Arylation of Phosphines with Aryl Bromides, Nat. Commun. 2022, 13, 2934.


98. Xiaowei Han, Minyan Wang, Yong Liang, Yue Zhao and Zhuangzhi Shi,* Regio- and Enantioselective Nucleophilic Addition to gem-Difluoroallenes, Nat. Synth. 2022, 1, 227.


97. Ziqi Zhu, Jieshuai Xiao, Mingjie Li and Zhuangzhi Shi,* Nickel-Catalyzed Intermolecular Asymmetric Addition of Aryl Iodides across Aldehydes, Angew. Chem. Int. Ed. 2022, 61, e202201370.


96. Hong Deng,§ Minyan Wang,§ Yong Liang, Xiangyang Chen, Tianhang Wang, Jonathan J. Wong, Yue Zhao, Kendall N. Houk and Zhuangzhi Shi,* Palladium-Catalyzed Stereospecific CP toward Diverse, Chem 2022, 8, 569.


95. Jiahang Lv and Zhuangzhi Shi,* Directed CH borylation: From Metal Catalysis to Metal Free,Chinese Science Bulletin. 2022, 67, 3824.

94. Jiahang Lv,§ Xue-Jun Zhang,§ Minyan Wang,* Yue Zhao and Zhuangzhi Shi,* BBr3-Mediated P(III)-Directed CH Borylation of Phosphines,Chem. Eur. J. 2022, 28, e202104100.


93. Ziqi Zhu, Lin Lin, Jieshuai Xiao and Zhuangzhi Shi,* Nickel-Catalyzed Stereo- and Enantioselective Cross-Coupling of gem-Difluoroalkenes with Carbon Electrophiles by CF Bond Activation, Angew. Chem. Int. Ed. 2022, 61, e202113209.


92. Huanhuan Luo, Dawei Wang, Minyan Wang* and Zhuangzhi Shi,* Rhodium-Catalyzed, Phosphorus(III)-Directed Hydroarylation of Internal Alkynes: Facile and Efficient Access to New Phosphine Ligands, Synlett 2022, 33, 351.


91. Jiefeng Hu,* Matthias Ferger, Zhuangzhi Shi,* and Todd B. Marder,* Recent Advances in Asymmetric Borylation by Transition Metal Catalysis. Chem. Soc. Rev. 2021, 50, 13129.


90. B. Prabagar,§ Youqing Yang,§ and Zhuangzhi Shi,* Site-Selective CH Functionalization to Access the Arene Backbone of Indoles and Quinolines, Chem. Soc. Rev. 2021, 50, 11249.


89. Cheng Chen,§ Minyan Wang,§ Hongjian Lu,* Binlin Zhao and Zhuangzhi Shi,* Enabling the Use of Alkyl Thianthrenium Salts in Cross-Coupling Reactions by Copper Catalysis, Angew. Chem. Int. Ed. 2021, 60, 21756.


88. Zedong Zhang, Jian Wen, Minyan Wang,* Chao-Guo Yan and Zhuangzhi Shi,* Green Synthesis of α-Deuterated Boronates Using DMTT Reagent, Green Synth. Catal. 2021, 2, 275.

87. Cheng Chen,§ Zheng-Jun Wang,§ Hongjian Lu, Yue Zhao and Zhuangzhi Shi,* Generation of Non-Stabilized Alkyl Radicals from Thianthrenium Salts for CB and CC Bond Formation, Nat. Commun. 2021, 12, 4526.

86. Binlin Zhao, Torben Rogge, Lutz Ackermann* and Zhuangzhi Shi,* Metal-Catalysed CHet (F, O, S, N) and CC Bond Arylation,Chem. Soc. Rev. 2021, 50, 8903.


85. Jiahang Lv,§ Binlin Zhao,§ Ying Han, Yu Yuan* and Zhuangzhi Shi,* Metal-Free Cascade Boron-Heteroatom Addition and Alkylation with Diazo Compounds, Chin. Chem. Lett. 2021, 32, 691.

84. Longlong Xi and Zhuangzhi Shi,* Enantioselective Nickel-Catalyzed 1,1-Arylboration of Terminal Olefins, Chin. J. Org. Chem. 2021, 41, 1264. (Highlight)

83. Yandong Wang,§ Jingyi Bai,§ Youqing Yang,§ Wenxuan Zhao, Yong Liang,* Di Wang, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalysed Selective CC Bond Activation and Borylation of Cyclopropanes, Chem. Sci. 2021, 12, 3599.


82. Jian Wen and Zhuangzhi Shi,* From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole CH Bonds, Acc. Chem. Res. 2021, 54, 1723.


81. ZhengJun Wang, Xiangyang Chen, Lei Wu, Jonathan J. Wong, Yong Liang, Yue Zhao, Kendall N. Houk* and Zhuangzhi Shi,* Metal-Free Directed CH Borylation of Pyrroles, Angew. Chem. Int. Ed. 2021, 60, 8500.


80. Dingyi Wang, Mingjie Li, Xiangyang Chen, Minyan Wang,* Yong Liang, Yue Zhao, Kendall N. Houk and Zhuangzhi Shi,* Palladium-Catalyzed Silacyclization of (Hetero)Arenes with a Tetrasilane Reagent through Twofold CH Activation, Angew. Chem. Int. Ed. 2021, 60, 7066.


79. Jiahang Lv,§ Binlin Zhao,§ Ying Hana,* Yu Yuan and Zhuangzhi Shi,* Metal-Free Cascade Boron-Heteroatom Addition and Alkylation with Diazo Compounds, Chin. Chem Lett. 2021, 32, 691.

78. Dingyi Wang,§ Xiangyang Chen,§ Jonathan J. Wong, Liqun Jin, Mingjie Li, Yue Zhao, K. N. Houk and Zhuangzhi Shi,* Phosphorus(III)-Assisted Regioselective CH Silylation of Heteroarenes, Nat. Commun. 2021, 12, 524.


77. Ben Dong,§ Jiasheng Qian,§ Mingjie Li,§ Zheng-Jun Wang, Minyan Wang, Dingyi Wang, Chengkai Yuan, Ying Han, Yue Zhao and Zhuangzhi Shi,* External Oxidant-Compatible Phosphorus(III)-Directed Site-Selective CH Carbonylation, Sci. Adv. 2020, 6, eabd1378.

77 -1.png

76. Huanhuan Luo,§ Yunfei Zhao,§ Dawei Wang,* Minyan Wang* and Zhuangzhi Shi,* Stereoselective Fluoroarylation of 1,1-Difluoroallenes Enabled by Palladium Catalysis, Green Synth. Catal. 2020, 1, 134.

75. Zexian Li, Minyan Wang and Zhuangzhi Shi,* Radical Addition Enables 1,2-Aryl Migration from Vinyl-Substituted All-Carbon Quaternary Center, Angew. Chem. Int. Ed. 2021, 60, 186.

74. Pan Gao,§ Liuzhou Gao,§ Longlong Xi,§ Zedong Zhang, Shuhua Li* and Zhuangzhi Shi,* Enantioselective Copper-Catalysed Defluorosilylation of Trifluoro-Methylated Alkenes with Silylboronates, Org. Chem. Front. 2020, 7, 2618.

73. Minyan Wang and Zhuangzhi Shi,* Methodologies and Strategies for Selective Borylation of CHet and CC Bonds, Chem. Rev. 2020, 120, 7348.

72. Yunfei Zhao, Jingyi Bai, Minyan Wang,* Hongjian Lu* and Zhuangzhi Shi,* Recent Advances in Methylating Agents, Sci Sin Chim. 2020, 50, 526. 

71. Jian Wen,§ Ben Dong,§ Jinjun Zhu, Yue Zhao and Zhuangzhi Shi,* Revealing Silylation of C(sp2)/C(sp3)–H Bonds in Arylphosphines by Ruthenium CatalysisAngew. Chem. Int. Ed. 2020, 5910909.

70. Minyan Wang, Yunfei Zhao, Yue Zhao and Zhuangzhi Shi,* Bioinspired Design of A Robust D3-Methylating Agent, Sci. Adv. 2020, 6, eaba0946. 

69. Binlin Zhao,* Xiaoyi Wu, Yu Yuan and Zhuangzhi Shi,* Copper-Catalysed Csp3-Csp Cross-Couplings between Cyclobutanone Oxime Esters and Terminal Alkynes Induced by Visible LightChem. Commun. 2020, 564676. 

68. Yandong Wang, Bailin Tian, Mengning Ding and Zhuangzhi Shi,* Electrochemical Cross‐Dehydrogenative Coupling between Phenols and β‐Dicarbonyl Compounds: Facile Construction of BenzofuransChem. Eur. J. 202026, 4297. 

67. Yixiao Wu,§ Binlin Zhao,§* Zhuangzhi Shi* and Yu Yuan,* Copper-Catalyzed Fragmentation-Rearrangement Sequence of Cycloketoxime Esters, Tetrahedron 2020, 76, 130873.

66. Jiahang Lv, Binlin Zhao, Yu Yuan, Ying Han and Zhuangzhi Shi,* Boron-Mediated Directed Aromatic C–H Hydroxylation, Nat. Commun. 202011, 1316. 


65. Jiahang Lv,§ Xiangyang Chen,§ Xiao-Song Xue, Binlin Zhao, Yong Liang, Minyan Wang, Liqun Jin, Yu Yuan, Ying Han, Yue Zhao, Yi Lu, Jing Zhao, Wei-Yin Sun, Kendall. N. Houk* and Zhuangzhi Shi,* Metal-Free Directed sp2-C–H Borylation, Nature 2019, 575, 336. 

64. Pan Gao, Guoqiang Wang, Longlong Xi, Minyan Wang, Shuhua Li* and Zhuangzhi Shi,* Transition-Metal-Free Defluorosilylation of Fluoroalkenes with Silylboronates, Chin. J. Chem. 201937, 1009. 

63. Binlin Zhao, Minyan Wang* and Zhuangzhi Shi,* Single-Electron-Transfer-Induced C(sp3)-N Couplings via C-C Bond Cleavage of Cycloketoxime Esters, J. Org. Chem. 2019, 84, 10145. 

62. Xiaowei Han, Jiefeng Hu, Cheng Chen, Yu Yuan and Zhuangzhi Shi,* Copper-Catalysed, Diboron-Mediated cis-Dideuterated Semihydrogenation of Alkynes with Heavy Water, Chem. Commun. 2019, 55, 6922. 

61. Xiaowei Han, Yu Yuan* and Zhuangzhi Shi,* Rhodium-Catalyzed Selective C-H Trideuteromethylation of Indole at C7 Position Using Acetic-d6 Anhydride, J. Org. Chem. 2019, 84, 12764

60. Dingyi Wang,§ Ben Dong,§ Yandong Wang, Jiasheng Qian, Jinjun Zhu, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalysed Direct Hydroarylation of Alkenes and Alkynes with Phosphines through Phosphorous-Assisted C-H Activation, Nat. Commun. 2019, 10, 3539. 

59. Dingyi Wang, Yunfei Zhao, Chengkai Yuan, Jian Wen, Yue Zhao and Zhuangzhi Shi,* Rhodium(II)-Catalyzed Dehydrogenative Silylation of Biaryl-Type Monophosphines with Hydrosilanes, Angew. Chem. Int. Ed. 2019, 58, 12529

58. Binlin Zhao,§ Zexian Li,§ Yixiao Wu, Yandong Wang, Jiasheng Qian, Yu Yuan and Zhuangzhi Shi,* An Olefinic 1,2-Boryl-Migration Enabled by Radical Addition: Construction of gem-Bis(boryl)alkanes, Angew. Chem. Int. Ed. 2019, 58, 9448

57. Panpan Wang,§ Binlin Zhao,§ Yu Yuan* and Zhuangzhi Shi,* Radical-Induced Ring-Opening and Reconstruction of Cyclobutanone Oxime Esters, Chem. Commun. 201955, 1971. 

56. Jian Wen, Dingyi Wang, Jiasheng Qian, Di Wang, Chendan Zhu, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalyzed PIII-Directed ortho-C-H Borylation of Arylphosphines, Angew. Chem. Int. Ed. 201958, 2078. 

55. Xiaodong Qiu,§ Panpan Wang,§ Dingyi Wang, Minyan Wang, Yu Yuan and Zhuangzhi Shi,* PIII-Chelation-Assisted Indole C7-Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis, Angew. Chem. Int. Ed. 2019, 58, 1504. 


54. Xiaodong Qiu, Hong Deng, Yue Zhao and Zhuangzhi Shi,* Rhodium-catalyzed, P-directed selective C7 arylation of indoles, Sci. Adv. 2018, 4, aau6468.  

53. Jiefeng Hu, Yue Zhao and Zhuangzhi Shi,* Highly Tunable Multi-Borylation of gem-Difluoroalkenes via Copper Catalysis, Nat. Catal. 20181, 860. 

52. Di Wang, Xiao-Song Xue, Kendall N. Houk* and Zhuangzhi Shi,* Mild Ring-Opening 1,3-Hydroborations of Non-Activated Cyclopropanes, Angew. Chem. Int. Ed. 201857, 16861.

51. Ting Wang, Liyan Zhou, Youqing Yang, Xinhao Zhang,* Zhuangzhi Shi,* and Yun-Dong Wu,* Directing Effects on the Copper-Catalyzed Site-Selective Arylation of  Indoles, Org. Lett. 2018, 20, 6502. 

50. Jiefeng Hu, Guoqiang Wang, Shuhua Li* and Zhuangzhi Shi,* Selective C-N Borylation of Alkyl Amines Promoted by Lewis Base, Angew. Chem. Int. Ed. 2018, 57, 15227. 

49. Binlin Zhao,§ Cheng Chen,§ Jiahang Lv, Zexian Li, Yu Yuan and Zhuangzhi Shi,* Photoinduced Fragmentation-Rearrangement Sequence of Cycloketoxime Esters, Org. Chem. Front. 2018, 5, 2719. 

48. Binlin Zhao, Hui Tan, Cheng Chen, Ning Jiao* and Zhuangzhi Shi,* Photoinduced C-C Bond Cleavage and Oxidation of Cycloketoxime Esters, Chin. J. Chem. 2018, 36, 995. 

47. Pan Gao, Chengkai Yuan, Yue Zhao and Zhuangzhi Shi,* Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes, Chem. 2018. 4, 2201. 

46. Jiahang Lv,§ Binlin Zhao,§ Li Liu, Ying Han,* Yu Yuan* and Zhuangzhi Shi,* Boron Trichloride-Mediated Synthesis of Indoles via the Aminoboration of Alkynes, Adv. Synth. Catal.2018. 360, 4054. 

45. Minyan Wang, Xinghui Pu, Yunfei Zhao, Panpan Wang, Zexian Li, Chendan Zhu and Zhuangzhi Shi,* Enantioselective Copper-Catalyzed Defluoroalkylation Using Arylboronate-Activated Alkyl Grignard Reagents, J. Am. Chem. Soc. 2018, 140, 9061. 

44. Arun Jyoti Borah and Zhuangzhi Shi,* Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization, J. Am. Chem. Soc. 2018140, 6062. 

43. Chendan Zhu, Di Wang, Dingyi Wang, Yue Zhao, Wei-Yin Sun and Zhuangzhi Shi,* Bottom-up Construction of π-Extended Arenes by a Palladium-Catalyzed Annulative Dimerization of o-Iodobiaryl Compounds,  Angew. Chem. Int. Ed. 201857, 8848. 

# Frontispiece artical.

42. Youqing Yang  and  Zhuangzhi Shi,* Regioselective Direct Arylation of Indoles on the Benzenoid Moiety,  Chem. Commun. 2018, 54, 1676. 

# Feature artical


41. Chendan Zhu, Dingyi Wang, Yue Zhao, Wei-Yin Sun, and Zhuangzhi Shi,* Enantioselective Palladium-Catalyzed Intramolecular α-Arylative Desymmetrization of 1,3-Diketones,  J. Am. Chem. Soc. 2017, 139, 16486. 

40. Jiefeng Hu,§ Xiaowei Han,§ Yu Yuan, and Zhuangzhi Shi,* Stereoselective Synthesis of Z-Fluoroalkenes by Copper-Catalyzed Hydrodefluorination of gem-Difluoroalkenes with Water,  Angew. Chem. Int. Ed. 2017, 56, 13342. 

39.Binlin Zhao, Zhuangzhi Shi,* Copper-Catalyzed Intermolecular Heck-Like Coupling of Cyclobutanone Oximes Initiated by Selective C-C Bond Cleavage, Angew. Chem. Int. Ed. 2017, 56, 12727.  

38. Xiaodong Qiu,§ Minyan Wang,§ Yue Zhao, Zhuangzhi Shi,* Rhodium(I)-Catalyzed Tertiary Phosphine Directed C-H Arylation: Rapid Construction of Ligand Libraries, Angew. Chem. Int. Ed. 2017, 56, 7233. 

37. Arun Jyoti Boraha, and Zhuangzhi Shi,* Palladium-Catalyzed Regioselective C-H Fluoroalkylation of Indoles at C4-Position, Chem. Commun. 2017, 53, 3945.

36. Youqing Yang,§ Pan Gao,§ Yue Zhao, and Zhuangzhi Shi,* Regiocontrolled Direct C-H Arylation of Indoles at the C4 and C5 Positions, Angew. Chem. Int. Ed. 2017, 56, 3966. (§Both authors contributed equally)

35. Jiefeng Hu, Minyan Wang, Xinghui Pu, and Zhuangzhi Shi,* Nickel-Catalyzed Retro-Hydroamidocarbonylation of Aliphatic Amides to Olefins, Nat. Commun. 2017, 8, 14993.  


34. Xinghui Pu, Jiefeng Hu, Yue Zhao, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation and Silylation of EstersACS Catal. 2016, 6, 6692.  

33. Chendan Zhu, Yue Zhao, Di Wang, Wei-Yin Sun and Zhuangzhi Shi,* Palladium-Catalyzed Direct Arylation and Cyclization of o-Iodobiaryls to A Library of Tetraphenylenes, Sci. Rep. 2016, 6, 33131.  

32. Youqing Yang, Ruirui Li, Yue Zhao, Dongbing Zhao, and Zhuangzhi Shi,* Cu-Catalyzed Direct C6-Arylation of Indoles, J. Am. Chem. Soc. 2016, 138, 8734.  

31. Pan Gao, Zhuangzhi Shi,* and Yu Yuan,* Iridium(III)-Catalyzed Regioselective Direct Arylation of sp2 C-H Bonds with Diaryliodonium Salts, Org. Biomol. Chem. 2016, 14, 7109. 

30. Jiefeng Hu, Yue Zhao, Jingjing Liu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C-N Bond Activation, Angew. Chem. Int. Ed. 201655, 8718. 

29. Binlin Zhao, Zhuangzhi Shi,* and Yu Yuan,* Transition-metal-catalyzed Chelation-assisted C–H Functionalization of Aromatic SubstratesChem. Rec. 2016, 16, 886.  

28. Yucheng Mu, Xiaodong Tan, Yemin Zhang, Xiaobi Jing, and Zhuangzhi Shi,* Pd(II)-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenesOrg. Chem. Front. 2016, 3, 380.  

# 2015 Emerging Investigators by OCF.

27. Youqing Yang, Xiaodong Qiu, Yue Zhao, Yucheng Mu, and Zhuangzhi Shi,* Palladium-Catalyzed C–H Arylation of Indoles at the C7-PositionJ. Am. Chem. Soc. 2016138, 495.   

# Top 2 most read articles from the 1 month list.

26. Jiefeng Hu, Heqing Sun, Wangshui Cai, Xinghui Pu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C-N Bond Cleavage, J. Org. Chem. 201681, 14.   

# JOC Featured Articles.

25. Invited Highlights: Yucheng Mu, Chendan Zhu, and Zhuangzhi Shi,* Memory of Chirality (MOC) in Intramolecular sp3 C-H Amination, Synlett 201627,486.   


24. Pan Gao, Wei Guo, Jingjing Xue, Yue Zhao, Yu Yuan, Yuanzhi Xia,* and Zhuangzhi Shi,* Iridium(III)-Catalyzed Direct Arylation of C-H Bonds with Diaryliodonium Salts, J. Am. Chem. Soc. 2015, 137, 12231 

# Top 5 most read articles from the 1 month list.

23. Chendan Zhu, Yong Liang, Xin Hong, Heqing Sun, Wei-Yin Sun, K. N. Houk,* and Zhuangzhi Shi,* Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C-H Amination: Reaction Development and Mechanistic InsightsJ. Am. Chem. Soc. 2015137, 7564 

# Top 20 most read articles from the 1 month list.

Highlighted by Synlett 2016, 27,486.

Before 2014

2011-2014 Postdoc Resarch

22. Z. Shi, M. Boultadakis-Arapinis, D. C. Koester, F. Glorius,* Rh(III)-Catalyzed Intramolecular Redox-Neutral Cyclization of Alkenes via C-H Activation, Chem. Comm. 2014, 50, 650-2652.  

21. D. Zhao,§ Z. Shi,§  F. Glorius,* Rh(III)-Catalyzed Hydrazine-Directed Redox-Neutral C-H Activation via the Cleavage of an N-N Bond: An General Access to Diverse Indoles, Angew. Chem. Int. Ed. 2013, 52, 12426-12429. (§ Both authors contributed equally)

20. Z. Shi, D. C. Koester, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds, J. Am. Chem. Soc. 2013, 135, 12204–12207.

19. Z. Shi, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Dehyrogenative Alkylation of (Hetero)Arenes with Allylic Alcohols, Allowing an Aldol Condensation to Indenes, Chem. Comm. 2013, 49, 6489-6491.  

18. Z. Shi, C. Grohmann, F. Glorius,* Mild Rh(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones:  Application to the Synthesis of the Homoprotoberberine Framework, Angew. Chem. Int. Ed. 2013, 52, 5393-5397. Synfacts, 2013, 9, 0828.

17. Z. Shi,§ M. Suri,§ F. Glorius,* Aerobic Synthesis of Pyrroles and Dihydropyrroles from Imines: Pd(II)-Catalyzed Intramolecular C-H Dehydrogenative Cyclization, Angew. Chem. Int. Ed. 2013, 52, 4892-4896. (§ Both authors contributed equally)

16. Z. Shi, F. Glorius,* Synthesis of Fluorenones via Quaternary Ammonium Salt-Promoted Intramolecular Dehydrogenative Arylation of Aldehydes, Chem. Sci. 2013, 4, 829-833. Synform, 2013, 13, A71.

15. Z. Shi, F. Glorius,* Efficient and Versatile Indole Synthesis from Enamines and Imines via Cross-Dehydrogenative Coupling, Angew. Chem. Int. Ed. 2012, 51, 9220-9222.

14. Z. Shi, N. Schroder, F. Glorius,* Rh[III]-Catalyzed Dehydrogenative Heck Reaction (DHR) of Salicylaldehydes, Angew. Chem. Int. Ed. 2012, 51, 8092-8096; Synfacts, 2012, 8, 1211.

2008-2011 Ph.D. Resarch

13. L. Ren, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Aerobic Oxidative Intramolecular Hydroamination and C-H Functionalization of N-Alkynyl Anilines for the Synthesis of Indole Derivatives, Tetrahedron 2013, 69, 4408-4414.

12. Z. Shi, C. Zhang, C. Tang, N. Jiao,* Recent Advances in Transition-metal Catalyzed Reactions Using Molecular Oxygen as the Oxidant, Chem. Soc. Rev. 2012, 41, 3381-3430.

11. Z. Shi,§ C. Tang,§ N. Jiao,* Chemoselective Synthesis of Naphthylamides and Isoquinolinones via Rhodium-Catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes, Adv. Syn. Cat. 2012, 354, 2695-2700. (§ Both authors contributed equally)

10. R. Lin, S. Ding, Z. Shi, N. Jiao,* An Efficient Difluorohydroxylation of Indoles Using Selectfluor as a Fluorinating Reagent, Org. Lett. 2011, 13, 4498-4501.

9. Z. Shi, B. Zhang, Y. Cui, N. Jiao,* Palladium-Catalyzed Ring-expansion Reaction of Indoles with Alkynes: From Indoles to Tetrahydroquinoline Derivatives Under Mild Conditions, Angew. Chem. Int. Ed. 2010, 49, 4036-4041.

8. S. Ding, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Synthesis of Carbolines by Iminoannulation of Internal Alkynes via Direct C?H Bond Cleavage Using Dioxygen as Oxidant, Org. Lett. 2010, 12, 1540-1543.

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