47. Pan Gao, Chengkai Yuan, Yue Zhao and Zhuangzhi Shi,* Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes, Chem. DOI:10.1016/j.chempr.2018.07.003 

46. Jiahang Lv,§ Binlin Zhao,§ Li Liu, Ying Han,* Yu Yuan* and Zhuangzhi Shi,* Boron Trichloride-Mediated Synthesis of Indoles via the Aminoboration of Alkynes, Adv. Synth. Catal. DOI:10.1002/adsc.201800509 

45. Minyan Wang, Xinghui Pu, Yunfei Zhao, Panpan Wang, Zexian Li, Chendan Zhu and Zhuangzhi Shi,* Enantioselective Copper-Catalyzed Defluoroalkylation Using Arylboronate-Activated Alkyl Grignard Reagents, J. Am. Chem. Soc. 2018, 140. 9061. 

44. Arun Jyoti Borah and Zhuangzhi Shi,* Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization, J. Am. Chem. Soc. 2018140. 6062. 

43. Chendan Zhu, Di Wang, Dingyi Wang, Yue Zhao, Wei-Yin Sun and Zhuangzhi Shi,* Bottom-up Construction of π-Extended Arenes by a Palladium-Catalyzed Annulative Dimerization of o-Iodobiaryl Compounds,  Angew. Chem. Int. Ed. 201853. 8848. 

# Frontispiece artical.

42. Youqing Yang  and  Zhuangzhi Shi,* Regioselective Direct Arylation of Indoles on the Benzenoid Moiety,  Chem. Commun. 2018, 54, 1676. 

# Feature artical


41. Chendan Zhu, Dingyi Wang, Yue Zhao, Wei-Yin Sun, and Zhuangzhi Shi,* Enantioselective Palladium-Catalyzed Intramolecular α-Arylative Desymmetrization of 1,3-Diketones,  J. Am. Chem. Soc. 2017, 139, 16486. 

40. Jiefeng Hu,§ Xiaowei Han,§ Yu Yuan, and Zhuangzhi Shi,* Stereoselective Synthesis of Z-Fluoroalkenes by Copper-Catalyzed Hydrodefluorination of gem-Difluoroalkenes with Water,  Angew. Chem. Int. Ed. 2017, 56, 13342. 

39.Binlin Zhao, Zhuangzhi Shi,* Copper-Catalyzed Intermolecular Heck-Like Coupling of Cyclobutanone Oximes Initiated by Selective C-C Bond Cleavage, Angew. Chem. Int. Ed. 2017, 56, 12727.  

38. Xiaodong Qiu,§ Minyan Wang,§ Yue Zhao, Zhuangzhi Shi,* Rhodium(I)-Catalyzed Tertiary Phosphine Directed C-H Arylation: Rapid Construction of Ligand Libraries, Angew. Chem. Int. Ed. 2017, 56, 7233. 

37. Arun Jyoti Boraha, and Zhuangzhi Shi,* Palladium-Catalyzed Regioselective C-H Fluoroalkylation of Indoles at C4-Position, Chem. Commun. 2017, 53, 3945.

36. Youqing Yang,§ Pan Gao,§ Yue Zhao, and Zhuangzhi Shi,* Regiocontrolled Direct C-H Arylation of Indoles at the C4 and C5 Positions, Angew. Chem. Int. Ed. 2017, 56, 3966. (§Both authors contributed equally)

35. Jiefeng Hu, Minyan Wang, Xinghui Pu, and Zhuangzhi Shi,* Nickel-Catalyzed Retro-Hydroamidocarbonylation of Aliphatic Amides to Olefins, Nature Commun. 2017, 8, 14993.  


34. Xinghui Pu, Jiefeng Hu, Yue Zhao, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation and Silylation of EstersACS Catal. 2016, 6, 6692.  

33. Chendan Zhu, Yue Zhao, Di Wang, Wei-Yin Sun and Zhuangzhi Shi,* Palladium-Catalyzed Direct Arylation and Cyclization of o-Iodobiaryls to A Library of Tetraphenylenes, Sci. Rep. 2016, 6, 33131.  

32. Youqing Yang, Ruirui Li, Yue Zhao, Dongbing Zhao, and Zhuangzhi Shi,* Cu-Catalyzed Direct C6-Arylation of Indoles, J. Am. Chem. Soc. 2016, 138, 8734.  

31. Pan Gao, Zhuangzhi Shi,* and Yu Yuan,* Iridium(III)-Catalyzed Regioselective Direct Arylation of sp2 C-H Bonds with Diaryliodonium Salts, Org. Biomol. Chem. 2016, 14, 7109. 

30. Jiefeng Hu, Yue Zhao, Jingjing Liu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C-N Bond Activation, Angew. Chem. Int. Ed. 201655, 8718. 

29. Binlin Zhao, Zhuangzhi Shi,* and Yu Yuan,* Transition-metal-catalyzed Chelation-assisted C–H Functionalization of Aromatic SubstratesChem. Rec. 2016, 16, 886.  

28. Yucheng Mu, Xiaodong Tan, Yemin Zhang, Xiaobi Jing, and Zhuangzhi Shi,* Pd(II)-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenesOrg. Chem. Front. 2016, 3, 380.  

# 2015 Emerging Investigators by OCF.

27. Youqing Yang, Xiaodong Qiu, Yue Zhao, Yucheng Mu, and Zhuangzhi Shi,* Palladium-Catalyzed C–H Arylation of Indoles at the C7-PositionJ. Am. Chem. Soc. 2016138, 495.   

# Top 2 most read articles from the 1 month list.

26. Jiefeng Hu, Heqing Sun, Wangshui Cai, Xinghui Pu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C-N Bond Cleavage, J. Org. Chem. 201681, 14.   

# JOC Featured Articles.

25. Invited Highlights: Yucheng Mu, Chendan Zhu, and Zhuangzhi Shi,* Memory of Chirality (MOC) in Intramolecular sp3 C-H Amination, Synlett 201627,486.   


24. Pan Gao, Wei Guo, Jingjing Xue, Yue Zhao, Yu Yuan, Yuanzhi Xia,* and Zhuangzhi Shi,* Iridium(III)-Catalyzed Direct Arylation of C-H Bonds with Diaryliodonium Salts, J. Am. Chem. Soc. 2015, 137, 12231 

# Top 5 most read articles from the 1 month list.

23. Chendan Zhu, Yong Liang, Xin Hong, Heqing Sun, Wei-Yin Sun, K. N. Houk,* and Zhuangzhi Shi,* Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C-H Amination: Reaction Development and Mechanistic InsightsJ. Am. Chem. Soc. 2015137, 7564 

# Top 20 most read articles from the 1 month list.

Highlighted by Synlett 2016, 27,486.

Before 2014

2011-2014 Postdoc Resarch

22. Z. Shi, M. Boultadakis-Arapinis, D. C. Koester, F. Glorius,* Rh(III)-Catalyzed Intramolecular Redox-Neutral Cyclization of Alkenes via C-H Activation, Chem. Comm. 2014, 50, 650-2652.  

21. D. Zhao,§ Z. Shi,§  F. Glorius,* Rh(III)-Catalyzed Hydrazine-Directed Redox-Neutral C-H Activation via the Cleavage of an N-N Bond: An General Access to Diverse Indoles, Angew. Chem. Int. Ed. 2013, 52, 12426-12429. (§ Both authors contributed equally)

20. Z. Shi, D. C. Koester, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds, J. Am. Chem. Soc. 2013, 135, 12204–12207.

19. Z. Shi, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Dehyrogenative Alkylation of (Hetero)Arenes with Allylic Alcohols, Allowing an Aldol Condensation to Indenes, Chem. Comm. 2013, 49, 6489-6491.  

18. Z. Shi, C. Grohmann, F. Glorius,* Mild Rh(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones:  Application to the Synthesis of the Homoprotoberberine Framework, Angew. Chem. Int. Ed. 2013, 52, 5393-5397. Synfacts, 2013, 9, 0828.

17. Z. Shi,§ M. Suri,§ F. Glorius,* Aerobic Synthesis of Pyrroles and Dihydropyrroles from Imines: Pd(II)-Catalyzed Intramolecular C-H Dehydrogenative Cyclization, Angew. Chem. Int. Ed. 2013, 52, 4892-4896. (§ Both authors contributed equally)

16. Z. Shi, F. Glorius,* Synthesis of Fluorenones via Quaternary Ammonium Salt-Promoted Intramolecular Dehydrogenative Arylation of Aldehydes, Chem. Sci. 2013, 4, 829-833. Synform, 2013, 13, A71.

15. Z. Shi, F. Glorius,* Efficient and Versatile Indole Synthesis from Enamines and Imines via Cross-Dehydrogenative Coupling, Angew. Chem. Int. Ed. 2012, 51, 9220-9222.

14. Z. Shi, N. Schroder, F. Glorius,* Rh[III]-Catalyzed Dehydrogenative Heck Reaction (DHR) of Salicylaldehydes, Angew. Chem. Int. Ed. 2012, 51, 8092-8096; Synfacts, 2012, 8, 1211.

2008-2011 Ph.D. Resarch

13. L. Ren, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Aerobic Oxidative Intramolecular Hydroamination and C-H Functionalization of N-Alkynyl Anilines for the Synthesis of Indole Derivatives, Tetrahedron 2013, 69, 4408-4414.

12. Z. Shi, C. Zhang, C. Tang, N. Jiao,* Recent Advances in Transition-metal Catalyzed Reactions Using Molecular Oxygen as the Oxidant, Chem. Soc. Rev. 2012, 41, 3381-3430.

11. Z. Shi,§ C. Tang,§ N. Jiao,* Chemoselective Synthesis of Naphthylamides and Isoquinolinones via Rhodium-Catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes, Adv. Syn. Cat. 2012, 354, 2695-2700. (§ Both authors contributed equally)

10. R. Lin, S. Ding, Z. Shi, N. Jiao,* An Efficient Difluorohydroxylation of Indoles Using Selectfluor as a Fluorinating Reagent, Org. Lett. 2011, 13, 4498-4501.

9. Z. Shi, B. Zhang, Y. Cui, N. Jiao,* Palladium-Catalyzed Ring-expansion Reaction of Indoles with Alkynes: From Indoles to Tetrahydroquinoline Derivatives Under Mild Conditions, Angew. Chem. Int. Ed. 2010, 49, 4036-4041.

8. S. Ding, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Synthesis of Carbolines by Iminoannulation of Internal Alkynes via Direct C?H Bond Cleavage Using Dioxygen as Oxidant, Org. Lett. 2010, 12, 1540-1543.

7. Z. Shi, Y. Cui, N. Jiao,* Synthesis of β- and γ-Carbolinones via Pd-Catalyzed Direct Dehydrogenative Annulation (DDA) of Indole-carboxamides with Alkynes Using Air as the Oxidant, Org. Lett. 2010, 12, 2908-2911.

6. Z. Shi, S. Ding, Y. Cui, N. Jiao,* A Palladium-Catalyzed Oxidative Cycloaromatization of Biaryls with Alkynes Using Molecular Oxygen as the Oxidant, Angew. Chem. Int. Ed. 2009, 48, 7895-7898.

5. Z. Shi, C. Zhang, S. Li, D. Pan, S. Ding, Y. Cui, N. Jiao,* Indoles from Simple Anilines and Alkynes: Palladium-Catalyzed C-H Activation Using Dioxygen as the Oxidant, Angew. Chem. Int. Ed. 2009, 48, 4572-4576, “Hot Paper”; Synfacts, 2009, 8, 846-846; “Nature China”highlight.

2005-2008 M.S. Resarch

4. F. Zhang, Z. Shi, F. Chen, Y. Yuan,* An Efficient MnCl2-catalyzed Tandem Acylation-Cross-coupling Reaction of o-Halobenzoyl Chloride with Diorganyl Magnesium Compound, Appl. Organometal. Chem. 2010, 24, 57-63.

3. Y. Yuan,* Z. Shi, Indium(III)-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Alkenes, Synlett 2007, 3219-3223.

2. Y. Yuan,* Z. Shi, X. Feng, X. Liu, Solvent-free Reactions of Alcohols with β-Dicarbonyl Compounds Catalyzed by Iron(III) Chloride, Appl. Organometal. Chem .2007, 21, 958-964.

1. 陈伟锋,史壮志,袁宇,颜朝国不对称自催化反应,化学进展, 200719,456。

2. 赵云霏、王敏燕、史壮志;一种二芳基并噻吩型或二芳基硫醚型氘代烷基制备方法;专利(申请)号:201810770921.4 

1. 邱晓东、王敏燕、赵越、史壮志;芳基取代联苯、吡咯、吲哚或联苯型单膦配体制备方法;专利(申请)号:201611201244.1