103. Longlong Xi, Liting Du and Zhuangzhi Shi,* Nickel-Catalyzed Reductive Cross-Coupling of Polyfluoroarenes with Alkyl Electrophiles by Site-Selective C–F Bond Activation,Chin. Chem. Lett. 2022, 33, 4287.

102. Lei Wu, Minyan Wang,* Yong Liang and Zhuangzhi Shi,* Ligand-Controlled Palladium-Catalyzed Regiodivergent Defluorinative Allylation of gem-Difluorocyclopropanes via σ-Bond Activation, Chin. J. Chem. 2022, 40, 2345.

101. Jiefeng Hu, Jiahang Lv and Zhuangzhi Shi,* Emerging Trends in C(sp3)–H Borylation, Trends Chem. 2022, 4, 685.

100. Ziqi Zhu and Zhuangzhi Shi,* Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides, Chin. J. Org. Chem. 2022, 42, 1872 (Highlight).

99. Dingyi Wang,§ Mingjie Li,§ Chengdong Shuang, Yong Liang, Yue Zhao, Minyan Wang and Zhuangzhi Shi,* Rhodium-Catalyzed Selective Direct Arylation of Phosphines with Aryl Bromides, Nat. Commun. 2022, 13, 2934.

98. Xiaowei Han, Minyan Wang, Yong Liang, Yue Zhao and Zhuangzhi Shi,* Regio- and Enantioselective Nucleophilic Addition to gem-Difluoroallenes, Nat. Synth. 2022, 1, 227.

97. Ziqi Zhu, Jieshuai Xiao, Mingjie Li and Zhuangzhi Shi,* Nickel-Catalyzed Intermolecular Asymmetric Addition of Aryl Iodides across Aldehydes, Angew. Chem. Int. Ed. 2022, 61, e202201370.

96. Hong Deng,§ Minyan Wang,§ Yong Liang, Xiangyang Chen, Tianhang Wang, Jonathan J. Wong, Yue Zhao, Kendall N. Houk and Zhuangzhi Shi,* Palladium-Catalyzed Stereospecific C–P toward Diverse, Chem 2022, 8, 569.

95. Jiahang Lv and Zhuangzhi Shi,* Directed C–H borylation: From Metal Catalysis to Metal Free,Chinese Science Bulletin. 2022, 67, 3824.

94. Jiahang Lv,§ Xue-Jun Zhang,§ Minyan Wang,* Yue Zhao and Zhuangzhi Shi,* BBr₃-Mediated P(III)-Directed C–H Borylation of Phosphines,Chem. Eur. J. 2022, 28, e202104100.

93. Ziqi Zhu, Lin Lin, Jieshuai Xiao and Zhuangzhi Shi,* Nickel-Catalyzed Stereo- and Enantioselective Cross-Coupling of gem-Difluoroalkenes with Carbon Electrophiles by C–F Bond Activation, Angew. Chem. Int. Ed. 2022, 61, e202113209.

92. Huanhuan Luo, Dawei Wang, Minyan Wang* and Zhuangzhi Shi,* Rhodium-Catalyzed, Phosphorus(III)-Directed Hydroarylation of Internal Alkynes: Facile and Efficient Access to New Phosphine Ligands, Synlett 2022, 33, 351.