91. Jiefeng Hu,* Matthias Ferger, Zhuangzhi Shi,* and Todd B. Marder,* Recent Advances in Asymmetric Borylation by Transition Metal Catalysis. Chem. Soc. Rev. 2021, 50, 13129.

90. B. Prabagar,§ Youqing Yang,§ and Zhuangzhi Shi,* Site-Selective C–H Functionalization to Access the Arene Backbone of Indoles and Quinolines, Chem. Soc. Rev. 2021, 50, 11249.

89. Cheng Chen,§ Minyan Wang,§ Hongjian Lu,* Binlin Zhao and Zhuangzhi Shi,* Enabling the Use of Alkyl Thianthrenium Salts in Cross-Coupling Reactions by Copper Catalysis, Angew. Chem. Int. Ed. 2021, 60, 21756.

88. Zedong Zhang, Jian Wen, Minyan Wang,* Chao-Guo Yan and Zhuangzhi Shi,* Green Synthesis of α-Deuterated Boronates Using DMTT Reagent, Green Synth. Catal. 2021, 2, 275.

87. Cheng Chen,§ Zheng-Jun Wang,§ Hongjian Lu, Yue Zhao and Zhuangzhi Shi,* Generation of Non-Stabilized Alkyl Radicals from Thianthrenium Salts for C–B and C–C Bond Formation, Nat. Commun. 2021, 12, 4526.

86. Binlin Zhao, Torben Rogge, Lutz Ackermann* and Zhuangzhi Shi,* Metal-Catalysed C–Het (F, O, S, N) and C–C Bond Arylation,Chem. Soc. Rev. 2021, 50, 8903.

85. Jiahang Lv,§ Binlin Zhao,§ Ying Han, Yu Yuan* and Zhuangzhi Shi,* Metal-Free Cascade Boron-Heteroatom Addition and Alkylation with Diazo Compounds, Chin. Chem. Lett. 2021, 32, 691.

84. Longlong Xi and Zhuangzhi Shi,* Enantioselective Nickel-Catalyzed 1,1-Arylboration of Terminal Olefins, Chin. J. Org. Chem. 2021, 41, 1264. (Highlight)

83. Yandong Wang,§ Jingyi Bai,§ Youqing Yang,§ Wenxuan Zhao, Yong Liang,* Di Wang, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalysed Selective C–C Bond Activation and Borylation of Cyclopropanes, Chem. Sci. 2021, 12, 3599.

82. Jian Wen and Zhuangzhi Shi,* From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole C–H Bonds, Acc. Chem. Res. 2021, 54, 1723.

81. ZhengJun Wang, Xiangyang Chen, Lei Wu, Jonathan J. Wong, Yong Liang, Yue Zhao, Kendall N. Houk* and Zhuangzhi Shi,* Metal-Free Directed C–H Borylation of Pyrroles, Angew. Chem. Int. Ed. 2021, 60, 8500.

80. Dingyi Wang, Mingjie Li, Xiangyang Chen, Minyan Wang,* Yong Liang, Yue Zhao, Kendall N. Houk and Zhuangzhi Shi,* Palladium-Catalyzed Silacyclization of (Hetero)Arenes with a Tetrasilane Reagent through Twofold C–H Activation, Angew. Chem. Int. Ed. 2021, 60, 7066.

79. Jiahang Lv,§ Binlin Zhao,§ Ying Hana,* Yu Yuan and Zhuangzhi Shi,* Metal-Free Cascade Boron-Heteroatom Addition and Alkylation with Diazo Compounds, Chin. Chem Lett. 2021, 32, 691.

78. Dingyi Wang,§ Xiangyang Chen,§ Jonathan J. Wong, Liqun Jin, Mingjie Li, Yue Zhao, K. N. Houk and Zhuangzhi Shi,* Phosphorus(III)-Assisted Regioselective C–H Silylation of Heteroarenes, Nat. Commun. 2021, 12, 524.